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Radiant exposure effects on physical properties of methacrylate - and silorane-composites
Catelan, Anderson; Kawano, Yoshio; dos Santos, Paulo Henrique; Ambrosano, Gláucia Maria Bovi; Bedran-Russo, Ana Karina & Aguiar, Flávio Henrique Baggio
Abstract
Aim:To evaluate the effect of different radiant exposures on the degree of conversion (DC),
Knoop hardness number (KHN), plasticization (P), water sorption (WS), and solubility (S) of
different monomer resin-based composites. Methods: Circular specimens (5 x 2 mm) were
manufactured from methacrylate and silorane composite resins, and light-cured at 19.8, 27.8,
39.6, and 55.6 J/cm2, using second-generation LED at 1,390 mW/cm2. After 24 h, DC was obtained
using a FT-Raman spectrometer equipped with a Nd:YAG laser, KHN was measured with 50-g
load for 15 s, and P was evaluated on the top and bottom surfaces by the percentage of hardness
reduction after 24 h immersed in absolute alcohol. WS and S were determined according to ISO
4049. Data were subjected to statistical analysis (α=0.05). Results: Methacrylate material presented
higher DC, KHN, P, and WS than silorane (p<0.05). There was no difference in the S values
(p>0.05). The increased radiant exposures improved only the KHN (p<0.05). In general, top
surfaces showed higher DC and KHN than bottom, for both materials (p<0.05). The increase of
the radiant exposure did not improve most physical properties of the composites and were monomerbase
dependent. Conclusions: Chemical composition of the composite resins resulted in different
physical properties behavior and could affect the clinical longevity of dental restorations, but overall
these properties were not influenced by the different radiant exposures evaluated in the study.
Keywords
composite resins; polymerization; physical properties
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