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Application of a high-surface-area schwertmannite in the removal of arsenate and arsenite
Song, J.; Jia, S.-Y.; Ren, H.-T.; Wu, S.-H. & Han, X.
Abstract
Schwertmannite is a poorly crystalline Fe(III)
hydroxide, which always shows high sorption capacities to
pollutants. In this study, schwertmannite synthesized from
the Fe3+ hydrolyzation method showed a hedgehog-like
shape, with a specific surface area of 325.5 m2 g-1, which
was much higher than that of the sphere-like schwertmannite
synthesized from the Fe2+ oxidation method, with
a specific surface area of 48.2 m2 g-1. The former was
then used to evaluate its sorption performance to As(V) and
As(III). Sorption of As(V) and As(III) could reach equilibrium
in 200 min, and the maximum sorption capacities
of As(V) and As(III) were 182.86 and 45.50 mg g-1 at pH
3.0, respectively, and 143.25 and 217.85 mg g-1 at pH 7.0,
respectively. Sorption capacity was dependent on pH and
more As(V) adsorbed on schwertmannite at lower pH,
while As(III) sorption increased with the increase of pH.
Our results also indicated that the presence of sulfate
reduced the sorption of As(V) from 85.4 to 67.6 mg g-1 as
sulfate concentration increased from 0.2 to 6 g L-1, while
such an effect was not apparent in As(III) sorption. Nitrate
and chloride did not show significant interference on the
sorption of both As(V) and As(III). Schwertmannite
showed better repeated uses in the removal of As(V) and
As(III) after seven repeated using cycles with removal
percentages of 95.3 % at pH 3.0 and 63.9 % at pH 7.0 to
As(V), and 31.0 % at pH 3.0 and 81.6 % at pH 7.0 to
As(III).
Keywords
Arsenite; Arsenate; Iron (hydr)oxide; Schwertmannite; Sorption
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