|
International Journal of Environment Science and Technology
Center for Environment and Energy Research and Studies (CEERS)
ISSN: 1735-1472 EISSN: 1735-1472
Vol. 13, No. 10, 2016, pp. 2339-2352
|
Bioline Code: st16217
Full paper language: English
Document type: Research Article
Document available free of charge
|
|
International Journal of Environment Science and Technology, Vol. 13, No. 10, 2016, pp. 2339-2352
en |
Removal of the radionuclides from aqueous solutions by biosorption on the roots of the dandelion ( Taraxacum officinale )
Fuks, L.; Oszczak, A.; Dudek, J.; Majdan, M. & Trytek, M.
Abstract
A novel biosorbent—dandelion root (DRB)—was investigated as adsorbent for removal of Sr(II) and
Am(III) from aqueous solutions. Batch equilibrium experiments
were carried out to study the effect of contact time,
initial concentration of the metal and pH of the media as
well as of the sorbent amount. The equilibrium time was
found to be 90 min for adsorption of both radionuclides.
The kinetic model can be described by the pseudo-second-order
model well, and the isotherm model is fitted to Freundlich
model the best. The maximum adsorption capacity
of the DRB at pH about 6.0 was calculated to be 63.7 and
80.6 g kg-1 for Sr(II) and Eu(III), respectively. About
90 % of Am(III) and 80 % of Sr(II) were removed when
30 mg of the biosorbent was used in 1 mL of the solution.
Use of the sequential portions of the fresh sorbent is
expected to increase efficiency of the process. Complexation
of Sr(II) and Am(III) by strong chelating agents, e.g.,
citrate, oxalate and EDTA, did not diminish significantly
the sorption efficiency of the sorbent. Once sorbed, <1 %
of each radionuclide was desorbed by water.
Graphical Abstract Low-cost biomass obtained from the
dandelions’ roots (DRB) was investigated as adsorbent for
removal of strontium and americium from aqueous
solutions.
Keywords
Americium-241; Aqueous contaminated solutions; Dandelion root; Isotherms; Metal ions biosorption; Radioactive wastes; Radionuclides; Strontium-85
|
|
© Copyright 2016 - Islamic Azad University Alternative site location: http://www.ijest.org
|
|