In this study, teff (
Eragrostis tef
) straw has been
chemically treated and tested as an adsorbent for Cr(VI)
removal. Chemically treatment of teff straw was done by
NaOH, H
3PO
4 and ZnCl
2 solutions. Scanning electron
micrograph and X-ray diffraction were used for anatomical
characterization, whereas Fourier transform infrared spectroscopy
was used for surface change characterization of
adsorbents. Effects of different experimental parameters
like pH (2–12), initial Cr(VI) concentration (100–900
mg/L), adsorbent dose (2.5–20 g/L), contact time
(15–360 min) and temperature (288–318 K) were studied.
Temperature increment was found to stimulate the
adsorption process. Langmuir isotherm was found to give
better representation over wide range of temperature for
untreated, H
3PO
4 as well as ZnCl
2-treated teff straw, and
Freundlich isotherm best represented the isotherm data for
NaOH-treated teff straw. Maximum Cr(VI) adsorption
capacity of untreated, NaOH-, H
3PO
4- and ZnCl
2-treated
teff straw was found to be 86.1, 73.8, 89.3 and 88.9 mg/g,
respectively. Respective values of average effective diffusion
coefficient (
De) were found to be 2.8 × 10
-13,
2.59 × 10
-14, 1.32 × 10
-13 and 1.14 × 10
-13 m
2/s,
respectively. The negative value of ∆
Go for all the adsorbents
indicates Cr(VI) spontaneous adsorption. Isosteric
heat of adsorption (∆
Hst,a) was found to vary with surface
coverage (
θ). ∆
Hst,a increased for untreated, H
3PO
4-
ZnCl
2-treated teff straw, and decreased steadily with
θ
for NaOH-treated teff straw.